Magnesium · Mining

The Pidgeon Process: Why Most Magnesium Is Made, Not Mined, in Batches

Magnesium is usually won from dolomite in a batch thermal reduction process that China scaled cheaply, not from a conventional continuous smelter.

Most of the world’s magnesium is produced by a specific thermal reduction method called the Pidgeon process, a real, distinctive chemistry that China scaled far more cheaply than anywhere else managed to.

The Pidgeon process reaction

Calcined dolomite is mixed with a reducing agent, usually ferrosilicon, and heated under vacuum, driving off magnesium vapour that condenses as crystalline metal:

2(MgO⋅CaO)+Si→2Mg↑+Ca2SiO42(MgO \cdot CaO) + Si \rightarrow 2Mg\uparrow + Ca_2SiO_4
The Pidgeon process reduction reaction, simplified. Calcined dolomite (MgO·CaO) reacts with silicon (supplied as ferrosilicon) under vacuum and heat, releasing magnesium as a vapour that is then condensed and cast, a batch process rather than a continuous one.
Batch
Process type
not continuous, unlike most smelting
Ferrosilicon
Main reducing agent
86%
China's share of world output

Why China’s version became so much cheaper

China built large numbers of comparatively small, low-capital Pidgeon process plants, often co-located with cheap coal power and ferrosilicon supply, and scaled this specific production model faster and more cheaply than the larger, more capital-intensive electrolytic magnesium plants historically used in the West. This is a real, documented industrial-strategy outcome, not a mineral-resource advantage, since the dolomite feedstock itself is not geographically scarce, covered on this material’s geology page.

Sources: Pidgeon process chemistry and China’s production-cost advantage draw on standard extractive metallurgy references (USGS, International Magnesium Association); production figures reference the production data elsewhere on this site.