Silicon · Mining

From Quartz to Chip-Grade Silicon: Three Purity Jumps, Not One

Silicon goes through a carbothermic smelt, then a chemical vapour purification, each step removing impurities the previous one could not touch.

Quartz mining itself is conventional quarrying, covered on this material’s geology page. Turning that quartz into the silicon grades covered on this material’s materials science page takes two further, genuinely distinct chemical processes.

Step one: carbothermic reduction

Quartz (SiO2) is reduced with carbon in an electric arc furnace at extreme temperature:

SiO2+2C→Si+2COSiO_2 + 2C \rightarrow Si + 2CO
The carbothermic reduction reaction producing metallurgical-grade silicon, roughly 98-99% pure, the grade used in aluminium alloys and silicones, covered on this material's application-wise page.

Step two: the Siemens process, for electronic grade

Metallurgical silicon is nowhere near pure enough for a semiconductor. It is converted to trichlorosilane gas, distilled repeatedly to strip trace impurities, then deposited back onto a pure silicon rod in a process called the Siemens process, reaching purities of 99.9999% or higher, covered on the materials science page for why this level of purity actually matters electronically.

1
Carbothermic reduction step
2
Siemens process distillation and deposition steps
Orders of magnitude
Purity jump required for electronics

Why polysilicon for solar is a separate, intermediate grade

Solar-grade polysilicon sits between metallurgical and full electronic grade, purer than metallurgical silicon but not requiring the extreme purity a microchip does, a real, distinct product tier that has become the largest single silicon end use by volume, covered on the application-wise page.

Sources: carbothermic reduction and Siemens process chemistry draw on standard extractive metallurgy and semiconductor materials references (USGS); production figures reference the production data elsewhere on this site.